After passing 4.48 liters of sulfur dioxide through the barium hydroxide solution, 252.8 g of potassium
After passing 4.48 liters of sulfur dioxide through the barium hydroxide solution, 252.8 g of potassium sulfite solution were obtained. Calculate the mass fraction in the resulting solution.
Let’s find the amount of the substance sulfur dioxide SO2.
n = V: Vn.
n = 4.48 L: 22.4 L / mol = 0.2 mol.
Let’s compose the reaction equation, find the quantitative ratios of substances.
2KOH + SO2 = K2SO3 + H2O.
According to the reaction equation, 1 mol of SO2 accounts for 1 mol of K2SO3. Substances are in quantitative ratios 1: 1.
n (K2SO3) = n (SO2) = 0.2 mol.
Let’s find the mass of K2SO3.
m = n × M,
M (K2SO3) = 158 g / mol.
m (K2SO3) = 158 g / mol × 0.2 mol = 31.6 g.
Find the mass fraction of K2SO3 in the solution.
W = m (substance): m (solution) × 100%,
W = (31.6 g: 252.8 g) 100% = 12.5%.
Answer: 12.15%.