An excess of sodium hydroxide was added to 250 ml of 32% nitric acid with a density of 1.2 g / ml.
An excess of sodium hydroxide was added to 250 ml of 32% nitric acid with a density of 1.2 g / ml. Determine the mass of the salt formed.
Given:
V (HNO3) = 250 ml
p (HNO3) = 1.2 g / ml
w% (HNO3) = 32%
To find:
m (salt) -?
Solution:
HNO3 + NaOH = NaNO3 + H2O, – we solve the problem based on the composed reaction equation:
1) Find the mass of the nitric acid solution:
m (HNO3) = p * V = 250 ml * 1.2 g / ml = 300 g
2) Find the mass of nitric acid in solution:
m (HNO3) = 300 g * 0.32 = 96 g
3) Find the amount of acid:
n (HNO3) = m: M = 96 g: 63 g / mol = 1.52 mol
4) We compose a logical expression:
if 1 mol of HNO3 gives 1 mol of NaNO3,
then 1.52 mol of HNO3 will give x mol of NaNO3,
then x = 1.52 mol.
5) Find the mass of sodium nitrate formed during the reaction:
m (NaNO3) = n * M = 1.52 mol * 85 g / mol = 129.2 g.
Answer: m (NaNO3) = 129.2 g.