An unknown alkene weighing 5.04 g completely discolors 100 g of a 9.6% solution
An unknown alkene weighing 5.04 g completely discolors 100 g of a 9.6% solution of bromine in carbon tetrachloride. Find the molecular formula for alkene.
1. Let’s compose the reaction equation for alkene bromination:
CnH2n + Br2 → CnH2nBr2;
2. find the mass of bromine:
m (Br2) = w (Br2) * m (solution) = 0.096 * 100 = 9.6 g;
3.Calculate the chemical amount of bromine:
n (Br2) = m (Br2): M (Br2) = 9.6: 160 = 0.06 mol;
4.According to the reaction equation, the amount of alkene coincides with the amount of added bromine:
n (CnH2n) = n (Br2) = 0.06 mol;
5.Calculate the molar mass of the alkene:
M (CnH2n) = m (CnH2n): n (CnH2n) = 5.04: 0.06 = 84 g / mol;
M (CnH2n) = 12n + 2n = 14n;
6.we equate the obtained molar masses and determine n:
14n = 84;
n = 6;
7.Substitute the found value of the index and write the formula:
C6H6.
Answer: hexene C6H6.