By neutralizing the sulfuric acid solution with ammonia, 1 liter of a solution (density 1.115 g / ml)
By neutralizing the sulfuric acid solution with ammonia, 1 liter of a solution (density 1.115 g / ml) of average salt containing 20% salt was obtained with a yield of 95%. Calculate the amount, mass and volume of ammonia used
1. Let’s compose the reaction equation:
2NH3 + H2SO4 = (NH4) 2SO4;
2. find the mass of the salt solution:
m (solution) = V (solution) * ρ = 1000 * 1.115 = 1115 g;
3.Calculate the mass of the resulting salt:
m ((NH4) 2SO4) = m (solution) * w ((NH4) 2SO4) = 1115 * 0.2 = 223 g;
4. calculate the practical and theoretical amount of ammonium sulfate:
ntract ((NH4) 2SO4) = m ((NH4) 2SO4): M ((NH4) 2SO4);
M ((NH4) 2SO4) = 14 * 2 + 8 + 32 + 4 * 16 = 132 g / mol;
npract ((NH4) 2SO4) = 223: 132 = 1.6894 mol;
ntheor ((NH4) 2SO4) = npract ((NH4) 2SO4): ν = 1.6894: 0.95 = 1.7783 mol;
5.determine the amount and volume of ammonia:
n (NH3) = ntheor ((NH4) 2SO4) * 2 = 1.7783 * 2 = 3.5566 mol;
V (NH3) = n (NH3) * Vm = 3.5566 * 22.4 = 79.67 dm ^ 3.
Answer: 79.67 dm ^ 3.