Calculate the mass fraction of potassium sulfide in 200 g of an aqueous solution
Calculate the mass fraction of potassium sulfide in 200 g of an aqueous solution if it is known that it has completely reacted with 248.25 g of a 20% solution of lead nitrate.
1. K2S + Pb (NO3) 2 = PbS + 2KNO3;
2.Calculate the mass of dissolved nitrate:
m (Pb (NO3) 2) = (w * m (Pb (NO3) 2 solution)): 100% = (248.25 * 20): 100% = 49.65 g;
3. find the amount of reactants:
M (Pb (NO3) 2) = 207 + 2 * 14 + 3 * 2 * 16 = 331 g / mol;
n (Pb (NO3) 2) = m: M = 49.65: 331 = 0.15 mol;
n (K2S) = 0.15 mol;
4. Find the mass of potassium sulfide:
M (K2S) = 39 * 2 + 32 = 110 g / mol;
m (K2S) = 0.15 * 110 = 16.5 g;
5.Calculate the mass concentration of sulfide in the initial solution:
w (K2S) = (m (K2S): m (K2S solution)) * 100% = (16.5: 200) * 100% = 8.25%.
Answer: 8.25%