Calculate the mass of potassium to be added to a 250 g serving of water to obtain a 20% potassium hydroxide solution.
1. The formation of potassium hydroxide proceeds according to the equation:
2K + 2H2O = 2KOH + H2 ↑;
2.Let us designate the chemical amount of potassium through the unknown variable x:
n (K) = x mol;
3.express the mass of potassium:
m (K) = M (K) * n (K) = 39x;
4.determine the amount and mass of the resulting potassium hydroxide:
n (KOH) = n (K) = x mol;
m (KOH) = n (KOH) * M (KOH) = 56x;
5.Set the mass of hydrogen released during the reaction:
n (H2) = n (K): 2 = 0.5x mol;
m (H2) = n (H2) * M (H2) = 0.5x * 2 = x g;
6. find the mass of the solution:
m (solution) = m (H2O) + m (K) – m (H2) = 250 + 39x – x = 250 + 38x;
7.express the mass fraction of potassium hydroxide and find the unknown x:
w (KOH) = m (KOH): m (solution);
0.2 = 56x: (250 + 38x);
50 + 7.6x = 56x;
48.4x = 50;
x = 1.033 mol;
8.Calculate the mass of potassium:
m (K) = 1.033 * 39 = 40.3 g.
Answer: 40.3 g.