Calculate the volume of sulfur dioxide (SO2) and how many molecules of potassium
Calculate the volume of sulfur dioxide (SO2) and how many molecules of potassium sulfite are formed during the decomposition of 180 g of potassium hydrogen sulfite (KHSO3).
Given:
m (KHSO3) = 180 g.
V (SO2) -?
N (K2SO3) -?
Solution:
Let’s find the amount of the substance KHSO3.
n = m: M.
M (KHSO3) = 120 g / mol.
n = 180 g: 120 g / mol = 1.5 mol.
Let’s find the quantitative ratios of substances.
2KHSO3 = K2SO3 + SO2 + H2O.
For 2 mol of KHSO3, there is 1 mol of SO2.
Substances are in quantitative ratios of 2: 1.
n (SO2) = ½ n (KHSO3) = 1.5: 2 = 0.75 mol.
V = n Vn, where Vn is the molar volume of gas equal to 22.4 l / mol.
V = 0.75 mol × 22.4 L / mol = 16.8 L.
N = n × NA, NA – Avogadro’s number, 6 × 10 ^ 23.
For 2 mol of KHSO3, there is 1 mol of K2SO3.
n (K2SO3) = ½ n (KHSO3) = 1.5: 2 = 0.75 mol.
N = 0.75 mol × 6 × 10 ^ 23 = 4.5 × 10 ^ 23.
Answer: 4.5 × 10 ^ 23; 16.8 l.