Citric acid in industry is obtained by microbiological fermentation of a glucose solution according to the equation
Citric acid in industry is obtained by microbiological fermentation of a glucose solution according to the equation: 2C6H12O6 + 3O2 – 2C6H8O7 + 4H2O How many kg of citric acid with a yield of 62% of the theoretically possible can be obtained from 520kg of 15% glucose solution?
Find the mass of glucose in the solution.
W = m (substance): m (solution) × 100%,
hence m (substance) = (m (solution) × w): 100%.
m (substance) = (520 kg × 15%): 100% = 78 kg.
Let’s find the amount of substance С6Н12О6.
n = m: M.
M (C6H12O6) = 180 kg / kmol.
n = 78 kg: 180 kg / kmol = 0.43 kmol.
Let’s find the quantitative ratios of substances.
2C6H12O6 + 3O2 → 2C6H8O7 + 4H2O.
For 2 kmol of С6Н12О6, there is 2 kmol of С6Н8О7.
Substances are in quantitative ratios 1: 1.
The amount of substances will be the same.
n (C6H12O6) = n (C6H8O7) = 0.43 kmol.
Let’s find the mass of С6Н8О7.
M (C6H8O7) = 192 kg / kmol.
m = n × M.
m = 192 kg / kmol × 0.43 kmol = 82.56 kg.
82.56 g of C6H8O7 were obtained according to calculations. According to the condition of the problem, the yield was 62%. Let’s find the mass of С6Н8О7 from the theoretically possible.
82.56 – 100%.
m – 62%.
m = (62% × 82.56%): 100% = 51.19 kg.
Answer: 51.19 kg.