Determine the mass fractions of metals in a mixture of iron and magnesium if it is known that when processing
Determine the mass fractions of metals in a mixture of iron and magnesium if it is known that when processing 0.4 g of this mixture with an excess of a mixture of hydrochloric acid 0.224 L of hydrogen
Let’s find the amount of the substance hydrogen.
n = V: Vn.
n = 0.224 L: 22.4 L / mol = 0.01 mol.
Mg + 2HCl = MgCl2 + H2.
Fe + 2HCl = FeCl2 + H2.
Let the amount of substance Mg – x mol, and Fe – y mol.
Then the mass of Mg will be 24x, and Fe – 56y. The mass of the mixture is 0.4 g. We obtain the equation
24 x + 56y = 0.4 g.
x + y = 0.01.
Let’s solve the system of equations.
{x + y = 0.01.
{24 x + 56y = 0.4.
x = 0.01 – y.
24 (0.01 – y) + 56y = 0.4.
0.24 – 24y + 56 y = 0.4.
0.24 – 0.4 = 24 y – 56 y.
– 0.16 = – 32 y.
y = -0.16: (- 32),
y = 0.005.
x = 0.01 – 0.005 = 0.005.
n (Mg) = 0.005 mol.
n (Fe) = 0.005 mol.
Let’s find the mass of Mg and Fe.
m = nM.
M (Mg) = 24 g / mol.
M (Fe) = 56 g / mol.
m (Mg) = 24 g / mol × 0.005 g / mol = 0.12 g.
m (Fe) = 56 g / mol × 0.005 g / mol = 0.28 g.
w (Mg) = (0.12: 0.4) × 100% = 30%
w (Fe) = (0.28: 0.4) × 100% = 70%.
Answer: 30%; 70%.