Determine the volume of nitrogen oxide 2 formed during the oxidation of 100 g of ammonia, if the yield is 85%.
Let’s find the amount of ammonia substance by the formula:
n = m: M.
M (NH3) = 17 g / mol.
n = 100 g: 17 g / mol = 5.88 mol.
Let’s compose the reaction equation, find the quantitative ratios of substances.
4NH3 + 5O2 = 4NO + 6H2O.
According to the reaction equation, 4 mol of ammonia accounts for 4 mol of nitrogen oxide. Substances are in quantitative ratios of 1: 1.
The amount of substance will be the same.
n (NH3) = n (NO) = 5.88 mol.
Find the volume of nitric oxide.
V = Vn n, where Vn is the molar volume of gas, equal to 22.4 l / mol, and n is the amount of substance.
V = 5.88 mol × 22.4 L / mol = 131.7 L.
131.7 liters were obtained according to calculations (theoretical yield).
According to the condition, the gas yield was 85%.
Let’s find a practical way out of the product.
131.7 g – 100%,
x g – 85%,
x = (131.7 × 85%): 100% = 111.95 liters.
Answer: 111.95 liters.