Find the formula for the crystalline hydrate of sodium hydroorstophosphate if it is known that the mass fraction
June 2, 2021 | education
| Find the formula for the crystalline hydrate of sodium hydroorstophosphate if it is known that the mass fraction (%) of phosphorus in the crystalline hydrate is 11.56%.
Given:
Na2HPO4 * xH2O
ω (P) = 11.56%
To find:
Na2HPO4 * xH2O -?
1) Mr (Na2HPO4 * xH2O) = N (P) * Ar (P) * 100% / ω (P) = 1 * 31 * 100% / 11.56% = 268.16 ≈ 268;
2) Mr (Na2HPO4) = Ar (Na) * N (Na) + Ar (H) * N (H) + Ar (P) * N (P) + Ar (O) * N (O) = 23 * 2 + 1 * 1 + 31 * 1 + 16 * 4 = 142;
3) Mr (xH2O) = Mr (Na2HPO4 * xH2O) – Mr (Na2HPO4) = 268 – 142 = 126;
4) Mr (H2O) = Ar (H) * N (H) + Ar (O) * N (O) = 1 * 2 + 16 * 1 = 18;
5) x = Mr (xH2O) / Mr (H2O) = 126/18 = 7;
The crystal hydrate formula is Na2HPO4 * 7H2O.
Answer: The formula of the crystalline hydrate is Na2HPO4 * 7H2O.
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