In 420 ml of water, 40 g of sulfur oxide (VI) was dissolved. Calculate the mass fraction of sulfuric acid in the resulting solution.
Given:
V (H 2 O) = 420 ml;
m (substance) = 40 g.
W -?
Decision:
Mass fraction of a substance is calculated by the formula:
W = m (substance): m (solution) × 100%,
m (substance) = (m (solution) × W): 100%,
one.
m (solution) = m (substance) + m (water).
Let’s find the mass of water by the formula.
m = Vp
m (H2O) = 420 ml × 1 g / ml = 420 g.
m (solution) = 420 g + 40 g = 460 g.
2. Let’s compose the reaction equation for the dissolution of sulfur oxide in water.
H2O + SO3 = H2SO4
3.Let’s find the amount of sulfur oxide substance by the formula:
n = m: M.
M (SO3) = 80 g / mol.
n = 40 g: 80 g / mol = 0.5 mol.
According to the reaction equation, 1 mol of sulfur oxide accounts for 1 mol of acid. Substances are in quantitative ratios 1: 1. Their amount of substances will be the same.
n (SO3) = n (H2SO4) = 0.5 mol.
4. Let’s find the mass of sulfuric acid.
m = n × M.
M (H2SO4) = 98 g / mol.
m = 98 g / mol × 0.5 mol = 49 g.
5. Let’s find the mass fraction of acid in the solution.
W = (49g: 460g) × 100% = 10.65% = 10.7%.
Answer: 10.7%.