Reduction of 90 g of acetaldehyde with hydrogen gave 82 g of ethyl alcohol. Determine the mass fraction of the alcohol yield.
1. CH3CHO + H2 → CH3CH2OH;
2. the initial reagent was an aldehyde, which means that all calculations from the data on it will be theoretical. Let’s find its chemical amount:
ntheor (CH3CHO) = m (CH3CHO): M (CH3CHO);
M (CH3CHO) = 12 + 3 + 12 + 1 + 16 = 44 g / mol;
ntheor (CH3CHO) = 2.045 mol;
3.the theoretical amount of ethanol will correspond to the amount of aldehyde:
ntheor (CH3CH2OH) = ntheor (CH3CHO) = 2.045 mol;
4. calculate the practical chemical amount according to the data for the reaction product:
ntrap (CH3CH2OH) = m (CH3CH2OH): M (CH3CH2OH);
M (CH3CH2OH) = 12 + 3 + 12 + 2 + 16 + 1 = 46 g / mol;
npt (CH3CH2OH) = 82: 46 = 1.783 mol;
5.Let’s find the alcohol output:
ν (CH3CH2OH) = ntract (CH3CH2OH): ntheor (CH3CH2OH);
ν (CH3CH2OH) = 1.783: 2.045 = 0.8719 or 87.19%.
Answer: 87.19%.