The mixture of ammonia and carbon monoxide was divided into two equal parts. When passing the first
The mixture of ammonia and carbon monoxide was divided into two equal parts. When passing the first part through a tube with incandescent copper (II) oxide, the mass of the tube decreased by 8.8 g, the second part can completely neutralize 147 g of 10% sulfuric acid. fraction of gases in the initial mixture
Let’s compose the reaction equalization:
CO + CuO = Cu + CO2. Reaction type: Double replacement
2NH3 + 3CuO = Na2 + 3Cu + 3H2O
2NH3 + H2SO4 = (NH4) 2SO4
The amount of ammonia substance is equal to:
V (H2SO4) = (147 * 0.1) 98 = 0.15 mol
V (NH3) = 2v (H2SO4) = 0.3 mol
The amount of carbon monoxide substance is equal to:
8.8 = m (CuO) -m (Cu) = m (O)
V (O) = 8.8 / 16 = 0.55 mol = V (CuO)
V (1 CuO) = 3 / 2V (NH3) = 0.45 mol
V (2CuO) = 0.55-0.45 = 0.1 mol
v (CO) = V2 (CuO) = 0.1 mol
Volume fractions of gases in the mixture
Omega (CO) = 0.1 / (0.1 + 0.3) * 100% = 25%
Omega (NH3) = 100% -25% = 75%
Answer: the volume fractions of gases were 25% and 75%