The relative density of hydrocarbon vapors with respect to nitrogen is 4. upon combustion of 11.2 g of this compound
The relative density of hydrocarbon vapors with respect to nitrogen is 4. upon combustion of 11.2 g of this compound, 35.2 g of carbon monoxide (4) and 14.4 g of water were formed. establish the molecular formula of this compound
1.Let’s find the mass of carbon atoms in 35.2 g of carbon dioxide.
Мr (СО2) = 44 g / mol.
44 g – 12 g (C),
35.2 g m (C).
m = (35.2 × 12): 44,
m = 9.6 g.
2.Let’s find the mass of hydrogen atoms in 14.4 g of water.
Мr (Н2О) = 18 g / mol.
18 g – 2 g (H),
14.4 g-m (H).
m = (14.4 × 2): 18,
m = 1.6 g.
m (substance) = 1.6 g + 9.6 g = 11.2 g.
Let’s find the amount of substance of carbon atoms, hydrogen.
n = m: M.
M (C) = 12 g / mol.
n (C) = 9.6 g: 12 g / mol = 0.8 mol.
n (H) = 1.6: 1 = 1.6 mol.
Let’s find the ratio of the amounts of the substance carbon and hydrogen.
C: H = 0.8: 1.6 = 1: 2.
Let’s find the molar mass of the hydrocarbon by the relative density.
Relative gravity is given as nitrogen. You need to multiply the molar mass of nitrogen by 4.
M (N2) = 14 × 2 = 28 g / mol.
D (nitrogen) = 4 × 28 = 112.
The molar mass of the hydrocarbon is 112. The ratio of carbon and hydrogen is 1: 2.
Let’s define the formula.
С8Н16 – octene.
M (C8H16) = 12 × 8 + 16 = 112 g / mol.