The vapor density of a monobasic carboxylic acid in terms of hydrogen is 37. What is the mass of potassium
The vapor density of a monobasic carboxylic acid in terms of hydrogen is 37. What is the mass of potassium hydroxide, which is required to neutralize 3.81 g of this acid?
1. Let’s write down the general formula for a monobasic carboxylic acid:
CnH2n + 1COOH;
2.Calculate the molecular weight of the acid:
Mr (CnH2n + 1COOH) = DH2 (CnH2n + 1COOH) * Mr (H2) = 37 * 2 = 74;
3. find the formula of carboxylic acid:
12n + 2n +1 + 12 + 33 = 74;
14n = 28;
n = 2, hence the formula C2H5COOH;
4. Let’s compose the equation of neutralization of propionic acid with potassium hydroxide:
C2H5COOH + KOH → C2H5COOK + H2O;
5.Calculate the amount of acid:
n (C2H5COOH) = m (C2H5COOH): M (C2H5COOH) = 3.81: 74 = 0.0515 mol;
6.determine the amount of potassium hydroxide and find its mass:
n (KOH) = n (C2H5COOH) = 0.0515 mol;
m (KOH) = n (KOH) * M (KOH);
M (KOH) = 39 + 17 = 56 g / mol;
m (KOH) = 0.0515 * 56 = 2.884 g.
Answer: 2.884 g.