What mass of iron can be obtained by hydrogen reduction of a mixture of ferum (2) oxide and ferum (3)
What mass of iron can be obtained by hydrogen reduction of a mixture of ferum (2) oxide and ferum (3) oxide weighing 110.4 grams, if the mass particles of oxides in the mixture are 13% and 87%, respectively?
1. Let us write down the equations of the reactions occurring during the reduction of iron from oxides:
FeO + H2 = Fe + H2O;
Fe2O3 + 3H2 = 2Fe + 3H2O;
2.Calculate the mass of oxides in the mixture:
m (FeO) = w (FeO) * m (mixtures) = 0.13 * 110.4 = 14.352 g;
m (Fe2O3) = w (Fe2O3) * m (mixture) = 0.87 * 110.4 = 96.048 g;
3.Calculate the chemical amounts of oxides:
n (FeO) = m (FeO): M (FeO);
M (FeO) = 56 + 16 = 72 g / mol;
n (FeO) = 14.352: 72 = 0.1993 mol;
n (Fe2O3) = m (Fe2O3): M (Fe2O3);
M (Fe2O3) = 2 * 56 + 3 * 16 = 160 g / mol;
n (Fe2O3) = 96.048: 160 = 0.6 mol;
4.Set the amounts of reduced iron in the first and second cases:
n1 (Fe) = n (FeO) = 0.1993 mol;
n2 (Fe) = n (Fe2O3) * 2 = 0.6 * 2 = 1.2 mol;
5. find the total amount of iron:
n (Fe) = n1 (Fe) + n2 (Fe) = 0.1993 + 1.2 = 1.3993 mol;
6.Calculate the mass of iron:
m (Fe) = n (Fe) * M (Fe) = 1.3993 * 56 = 78.36 g.
Answer: 78.36 g.