With the action of excess water on 7.6 grams of a mixture of sodium hydride and potassium hydride
With the action of excess water on 7.6 grams of a mixture of sodium hydride and potassium hydride, 5.6 liters of hydrogen were obtained. Determine the mass composition of the initial mixture.
NaH + H2O = NaOH + H2
KH + H2O = KOH + H2
Let the mass of sodium hydride be x, the mass of potassium hydride – y.
By condition: x + y = 7.6 g
Let’s find the molar mass of hydrides.
n (NaH) = m (NaH) / M (NaH) = x / 24
n (KH) = m (KH) / M (KH) = y / 40
n (NaH) = n1 (H2) – in the first reaction.
n (KH) = n2 (H2) – in the second reaction.
Let’s find the total amount of moles of released hydrogen.
n (H2) = V (H2) / Vm = 5.6 / 22.4 = 0.25 mol
n1 (H2) + n2 (H2) = n (H2) = 0.25
x / 24 + y / 40 = 0.25
We solve the system of equations:
x + y = 7.6
x / 24 + y / 40 = 0.25
Hence y = 3.86 g, x = 3.74 g.