Write down the hydrolysis equations in molecular and ionic form, indicate
Write down the hydrolysis equations in molecular and ionic form, indicate the medium and type of hydrolysis for the following salts: Al2S3, K2S, FeCl2, CaCl2
Let’s compose the equations:
1) Al2S3 = 2Al3 + 3S2;
HOH = H + + OH-;
Al2S3 + 6H2O = 2Al (OH) 3 + 3H2S;
Complete hydrolysis. Wednesday neutral PH = 7.
2) K2S = 2K + + S2-;
2K + + S2- + H2O = K + + OH- + K + + HS- – complete ionic equation;
S2- + H2O = HS- + OH- – abbreviated equation;
K2S + H2O = KOH + KHS – molecular equation;
Alkaline medium pH> 7.
3) FeCl2 = Fe2 + + 2Cl-;
Fe2 + + 2Cl- + H2O = FeOH + + Cl- + H + + Cl;
FeOH + + H2O = Fe (OH) 2 + H +;
FeCl2 + H2O = Fe (OH) Cl + HCl;
Acidic medium pH <7.
4) CaCl2 = Ca2 + + 2Cl-;
Ca2 + + 2Cl- + H2O = CaOH + + Cl- + H + + Cl-;
Ca2 + + H2O = CaOH + + H +;
CaCl2 + H2O = Ca (OH) Cl + HCl;
Acidic medium pH <7.