Write the equation of reactions with which you can carry out the chain of transformation of substances.
Write the equation of reactions with which you can carry out the chain of transformation of substances. If this is a rio, then write a complete and abbreviated one. If it is an ovre Iron oxide 2 – Sodium dixoferrate III – Iron chloride III – Iron hydroxide III – Potassium ferrate – Iron sulfate III – Iron oxide III – Iron sulfate III – Iron III-potassium hexacyanoferrate II
Fe2O3 → NaFeO2 → FeCl3 → Fe(OH)3 → K2FeO4 → Fe2(SO4)3 → Fe2O3 → Fe2(SO4)3 → Fe4[Fe(CN)6]3
1) Fe2O3 + 2NaOH → 2NaFeO2 + H2O;
2) 2NaFeO2 + 4HCl → NaCl + FeCl3 + 2H2O;
3) FeCl3 + 3KOH → Fe(OH)3↓ + 3KCl;
Fe3+ + 3Cl– + 3K+ + 3OH– → Fe(OH)3↓ + 3K+ + 3Cl-;
Fe3+ + 3OH– → Fe(OH)3↓;
4) 2Fe(OH)3↓ + 3Cl2 + 10KOH → 2K2FeO4 + 6KCl + 8H2O;
+3 -2+1 0 +1-2+1 +1 +6-2 +1-1 +1 -2
2Fe(OH)3↓ + 3Cl2 + 10KOH → 2K2FeO4 + 6KCl + 8H2O;
2Cl + 2e → 2Cl
5) 2K2FeO4 + 10H2SO4 → 2Fe2(SO4)3 + 2K2SO4 + 3O2 + 10H2O;
+1 +6-2 +1+6-2 +3 +6-2 +1 +6-2 0 +1 -2
2K2FeO4 + 10H2SO4 → 2Fe2(SO4)3 + 2K2SO4 + 3O2 + 10H2O;
6) Fe2(SO4)3 → Fe2O3 + 3SO3;
7) Fe2O3 + 3H2SO4 → Fe2(SO4)3 + 3H2O;
8) Fe2(SO4)3 + 2K4[Fe(CN)6] → 2KFe[Fe(CN)6] + 3K2SO4;
2Fe3+ + 3SO42- + 8K+ + 2[Fe(CN)6]-4 → 2KFe[Fe(CN)6] + 6K+ + SO42-.